Manuscript Number : IJSRSET151673

Synthesisation of 2223 Superconductors

Authors(2) :-Rohitash kumar, H.S.Singh

To preparation of superconductors with structure type of Bi2Sr2Can-1CunOx (n=1, 2, 3), with formula (Bi2M1+nTMnOx) where M= Sr, Ba, Ca transition matel. The composition Bi2Sr2Can-1CunOx were prepared by solid state reaction by Ball Mill from the principle routs like Bi-2223, Ca2CO3 and CuO with high purity of 99.99%. Different measurement such as resistivity measurement, X-Ray Diffraction and FTIR were made to changes in superconductivity. Some transition matel (M) other than Cu, reported belongs to group which contain transition metal such as iron, cobalt, manganese etc. The lattice constant obtained with Fe doped in different amounts. The Tc of the high temperature superconducting cuprate Bi2Sr4-xCaxFe3-yCuyOz were obtained 157K, the resistance decreases nearly zero with decreases temperature.

Authors and Affiliations

Rohitash kumar
Department of Physics, Faculty of Science, Jai Narain Vyas University, Jodhpur Rajasthan, India
H.S.Singh
Department of Physics, Faculty of Science, Jai Narain Vyas University, Jodhpur Rajasthan, India

Bi­2Sr4-xCaxFe3-yCuyOz , ball mill, Fe doping, Electrical Resistivity, XRD, FTIR, MÖssbauer spectroscopy .

  1. Maeda H, Tanaka Y, Fukutomi M, Asano T (1988). A new high-Tc oxide superconductor without a rare earth element, Jpn. J. Appl. Phys. 27:L209-L210.
  2. S.Uchida et al. Jpn. J.Appl. Phy . 26L1 (1987).
  3. H. Takagi, S. Uchida et al. Jpn. J.Appl. Phy . 26L123 (1987).
  4. H.S. singh and Rohitash kumar, international conference on ceramic, Bikaner, india IJMPCS world scientific publication, Vol. 22 (2013) 35-36.
  5. H.W. Zandbergen et al. Nature 332 620 (1988).
  6. H. Kamerlingh Onnes, research notebooks 56, Kamerlingh oness Archive, Berhaave Museum, Leiden, the Netherlands.
  7. Koyoma S, Endo U, Kawai T (1988). “Formation of high Tc phase of  Bi-Pb-Sr-Ca-Cu-O superconductors”, Proceeding of the 1st international symposium on superconductivity, Tokyo Berlin, 88: 833-836.
  8. H.S. singh & Rohitash kumar, international conference on ceramic, Bikaner, india IJMPCS world scientific publication, Vol. 22 (2013) 35-36.
  9. Widad M. Faisal and Salwan K. J. Al-Ani, “Enhanced superconducting properties of the Pb doped trilayer high-temperature (Bi2Sr2Can-1CunO2n+4δ) cuprate superconductor” International Journal of the Physical Sciences Vol. 7(2), pp. 171 - 181, 9 January, 2012.
  10. Rohitash Kumae and H.S.Singh, “Spectroscopic Study on Iron Oxide Based Bi-2223         Superconductors” INTERNATIONAL JOURNAL OF SCIENTIFIC PROGRESS AND RESEARCH (IJSPR), Volume-15, Number - 01, 2015.
  11. K. Iida, S. Haindl, T. Thersle, J. Ha¨nisch, F. Kurth, M. Kidszun, R. Hu¨hne, I. Mo¨nch, L. Schultz, B. Holzapfel, and R. Heller: Appl. Phys. Lett. 97 (2010) 172507.
  12. T. Katase, H. Hiramatsu, V. Matias, C. Sheehan, Y. Ishimaru, T. Kamiya, K. Tanabe, and H. Hosono: Appl. Phys. Lett. 98 (2011) 242510.
  13. K. H. Tan, “Principles of soil chemistry,” Mariel Dekker Inc., New York, USA, 1998.
  14. G. Parthasarathy, “Effect of High-Pressures on the Electrical Resistivity of Natural Zeolites from the Deccann Trap, Mahrashtra, India,” Journal of Applied Geophysics Vol. 58, No. 4, pp. 321-329.
  15. H. Frauenfelder, The Mössbauer Effect, W.A. Benjamin, New York, 1962. (QC 490 F7).
  16. R.L. Mössbauer, Z. Physik 151, 124 (1958). Later review paper: R.L. Mössbauer, Recoilless nuclear resonance absorption, Ann. Rev. Nuclear Sci. 12, 123 (1962).
  17. R.M. Hazen, L. W. Finger, R. J. Angel, C. T. Prewitt, N.L. Ross, H. K. Mao, C. G. Hadiddiacos, P.H. Hor, R.L. Meng, C.W. Chu, Phys Rev. 835 7137 (1987).
  18. T. Siegrist, S. Sunshine, D.w. Murphy, R.J. Cava, S.M. Zahurak, Phys. Rew. 835 7137 (1987).
  19. J.D. Jorgensen, H.B. Schutter, D.G. Hinks, D.W. Capone ii, K. Zhang, M.B. Brodsky, D.J. Scalapino, Phys. Rew. Lett. 58 1024 (1987).
  20. Hoydoo You, R.K. Mcmillan, J.D. Axe, D.E. Cox J.Z. Liu, G.W. Crabtree and G.J. Lam < Sol. St Com. 64 739 (1987).
  21. P. Boolchand and D. McDaniel, Studies of High Temperature superconductors Ed. A.V. Narlikar Vol. 4, Nova, New York.
  22. H.S. Singh, Rohitash Kumar, MÖssbauer Spectroscopic Study of the Mahadevpur Meteorite Arunachal Pradesh and Assam, J. Pure Appl. & Ind. Phys. Vol.3 (2), 138-141 (2013).
  23. H.S. Singh, Rohitash kumar, “MÖSSBAUER SPECTROSCOTIC STUDY OF CHEMICAL STATE OF IRON IN NATURAL SAMPLES HORNBLENDES FROM UDAIPUR DISTRIC (RAJ)”,  International Journal of Scientific & Engineering Research, Volume 5, Issue 7,1114-1115 July-2014.

Publication Details

Published in : Volume 1 | Issue 6 | November-December 2015
Date of Publication : 2015-12-30
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 395-403
Manuscript Number : IJSRSET151673
Publisher : Technoscience Academy

Print ISSN : 2395-1990, Online ISSN : 2394-4099

Cite This Article :

Rohitash kumar, H.S.Singh, " Synthesisation of 2223 Superconductors, International Journal of Scientific Research in Science, Engineering and Technology(IJSRSET), Print ISSN : 2395-1990, Online ISSN : 2394-4099, Volume 1, Issue 6, pp.395-403, November-December-2015. Journal URL : https://res.ijsrset.com/IJSRSET151673

Article Preview